Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)(5)Chippindale, A. M., Hibble, S. J., Pohl, A. H. and Bilbe, E. J. (2006) Dicaesium pentacyanotricuprate(I), Cs2Cu3(CN)(5). Acta Crystallographica Section E: Structure Reports Online, 62 (7). i140-i142. ISSN 1600-5368 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1107/s1600536806020484 Abstract/SummaryCs2Cu3(CN)(5) has a layered structure consisting of [Cu-3(CN)(5)](2-) sheets stacked in an ABAB fashion along the c axis, with Cs+ cations lying between the sheets. The sheets are generated by linking -(CuCN) - chains, in which the C N groups are ordered, via [Cu(CN)(3)](2-) units. The two bridging cyanide groups of each [Cu(CN)(3)](2-) unit show partial 'head-to-tail' disorder of C and N, whilst the third C N group is terminal and ordered with C bonded to Cu.
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