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Catena-Poly[bis(ethane-1,2-diammonium) [manganese(II)-di-mu-phosphato-kappa O-4 : O ']]: a one-dimensional manganese phosphate

Gaslain, F.O.M. and Chippindale, A.M. (2007) Catena-Poly[bis(ethane-1,2-diammonium) [manganese(II)-di-mu-phosphato-kappa O-4 : O ']]: a one-dimensional manganese phosphate. Acta Crystallographica Section C, 63 (11). M537-M540 . ISSN 0108-2701

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To link to this item DOI: 10.1107/S0108270107048111

Abstract/Summary

The title compound,{(C2H10N2)(2)[Mn(PO4)(2)]}(n), contains anionic square-twisted chains of formula [Mn(PO4)(2)](4-) constructed from corner-sharing four-membered rings of alternating MnO4 and PO4 units. The Mn and P atoms have distorted tetrahedral coordination and the Mn atom lies on a twofold axis. The linear manganese-phosphate chains are held together by hydrogen-bonding interactions involving the framework O atoms and the H atoms of the ethane-1,2-diammonium cations, which lie in the interchain spaces.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11264
Uncontrolled Keywords:HYDROTHERMAL SYNTHESIS, HYDROGEN-PHOSPHATE, CRYSTAL-STRUCTURE, MAGNETIC-PROPERTIES, ZINC PHOSPHATES, CHAIN, DIFFRACTION

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