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Electrochromic and electrofluorochromic properties of a new boron dipyrromethene–ferrocene conjugate

Galangau, O., Fabre-Francke, I., Munteanu, S., Dumas-Verdes, C., Clavier, G., Méallet-Renault, R., Pansu, R.B., Hartl, F. and Miomandre, F. (2013) Electrochromic and electrofluorochromic properties of a new boron dipyrromethene–ferrocene conjugate. Electrochimica Acta, 87. pp. 809-815. ISSN 0013-4686

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To link to this item DOI: 10.1016/j.electacta.2012.09.048

Abstract/Summary

A new boron dipyrromethene–ferrocene (BODIPY–Fc) conjugate with pentafluorophenyl as the meso substituent and two Fc termini was synthesized and its spectroscopic and electrochemical features were analyzed. An intramolecular charge transfer from the donor Fc to the acceptor BODIPY has been predicted by theory and confirmed experimentally, leading to efficient fluorescence quenching when the dyad is in the neutral state. Fluorescence can be triggered by oxidizing both ferrocenyl units either chemically or electrochemically. Eventually, a fully reversible fluorescence switch is evidenced by coupling TIRF microscopy with electrolysis in an electrochemical cell.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:30231
Uncontrolled Keywords:Boron dipyrromethene; Ferrocene; Electrochromic; Fluorescence; Redox switch
Publisher:Elsevier

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