Accessibility navigation


In situ surface analysis of palladium-platinum alloys in methane oxidation conditions

Large, A. I., Bennett, R. A. ORCID: https://orcid.org/0000-0001-6266-3510, Eralp-Erden, T. and Held, G. (2022) In situ surface analysis of palladium-platinum alloys in methane oxidation conditions. Faraday Discussions. ISSN 1364-5498

[img]
Preview
Text (Open Access) - Published Version
· Available under License Creative Commons Attribution.
· Please see our End User Agreement before downloading.

4MB
[img] Text - Accepted Version
· Restricted to Repository staff only

12MB

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1039/D1FD00113B

Abstract/Summary

Palladium and palladium-platinum foils were analysed using temperature-programmed near-ambient pressure x-ray photoelectron spectroscopy (TP-NAP-XPS) under methane oxidation conditions. Oxidation of palladium is inhibited by the presence of water, and in oxygen-poor environments. Pt addition further inhibits oxidation of palladium across all reaction conditions, preserving metallic palladium to higher temperatures. Bimetallic foils underwent significant restructuring under reaction conditions, with platinum preferentially migrating to the bulk under select conditions.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:105100
Publisher:Royal Society of Chemistry

Downloads

Downloads per month over past year

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation