Accessibility navigation


Bis[bis(methoxycarbimido)aminato]copper(II) 1-methylpyrrolidin-2-one disolvate

Chippindale, A.M., Bilbe, E.J. and Hibble, S.J. (2009) Bis[bis(methoxycarbimido)aminato]copper(II) 1-methylpyrrolidin-2-one disolvate. Acta Crystallographica Section C-Crystal Structure Communications, 65 (12). M485-M487. ISSN 0108-2701

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1107/s0108270109048252

Abstract/Summary

The title compound, [Cu(C4H8N3O2)(2)]center dot 2C(5)H(9)NO, consists of a neutral copper complex, in which the Cu II centre coordinates to two bis(methoxycarbimido) aminate ligands, solvated by two molecules of 1-methylpyrrolidin-2-one. The complex is planar and centrosymmetric, with the Cu II centre occupying a crystallographic inversion centre and adopting approximately square-planar geometry. N-H center dot center dot center dot O hydrogen-bonding interactions exist between the amine NH groups of the ligands and the O atoms of the 1-methylpyrrolidin-2-one molecules. The associated units pack to form sheets.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11128
Uncontrolled Keywords:COMPLEXES, METHANOL, BIS(METHOXYCARBIMIDO)AMINE, DICYANAMIDE, TRINUCLEAR, MOTIFS, ANION, MP2

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation