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A novel copper(I) complex that is a monomeric single helix in solid state but a dimeric double helix in solution

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Chowdhury, S., Iveson, P.B., Drew, M.G.B., Tocher, D.A. and Datta, D. (2003) A novel copper(I) complex that is a monomeric single helix in solid state but a dimeric double helix in solution. New Journal of Chemistry, 27 (2). pp. 193-196. ISSN 1144-0546

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To link to this item DOI: 10.1039/b207057j

Abstract/Summary

Single helical [(CuL)-L-I]ClO4.12CH(2)Cl(2) (L=1:2 condensate of benzil dihydrazone and 2-acetylpyridine) unfolds and coils up in CH2Cl2 solution to generate double helical [(Cu2L2)-L-I](2+).

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11140
Uncontrolled Keywords:MOLECULAR STRANDS, METAL, CHROMOPHORE, OLIGOMERS, HELICATE, ACID
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