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Intercalation of diiodine molecules in cis-Ru(bpy)(2)Cl-2

Nag, S., Drew, M.G.B. and Datta, D. (2006) Intercalation of diiodine molecules in cis-Ru(bpy)(2)Cl-2. Inorganic Chemistry Communications, 9 (3). pp. 310-312. ISSN 1387-7003

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To link to this item DOI: 10.1016/j.inoche.2005.12.005


Reaction of diiodine with cis-Ru(bpy)(2)Cl-2 in methanol at room temperature yields a thermally stable intercalate cis-Ru(bpy)(2)Cl-2 center dot 1.7I(2) (1) which has been characterised by X-ray crystallography. Iodine is leeched from 1 as it reacts with acetone at room temperature. (C) 2005 Elsevier B.V. All rights reserved.

Item Type:Article
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11523
Uncontrolled Keywords:ruthenium(II), intercalation, iodine, crystal structure, CRYSTAL-STRUCTURE, IODINE, POLYIODIDE, COMPLEXES, OXIDATION, CHAINS, STATE

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