Synthesis, crystal structure and thermal studies of catena(L-glutamato)-aqua copper(II) monohydrateRay, M. S., Drew, M.G.B. and Ghosh, A. (2004) Synthesis, crystal structure and thermal studies of catena(L-glutamato)-aqua copper(II) monohydrate. Journal of the Indian Chemical Society, 81 (7). pp. 543-546. ISSN 0019-4522 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. Official URL: http://indianchemsoc.org/ Abstract/SummaryThe synthesis. crystal structure and thermal study of the blue catena-(L-glutamato)-aqua copper(II) monohydrate have been reported. The compound crystallizes in P2(1)2(1)2(1) space group and consists of a polymeric three-dimensional network of copper(II) which is coordinated with the amino nitrogen and the carboxylate oxygen Of L-glutamate, the side chain carboxylate oxygen of a neighbouring L-glutamate and the oxygen of a water molecule in the equatorial position. Weak coordination of two additional glutamate oxygen atoms to both the axial positions Completes a distorted octahedron. The crystal structure shows that the lattice water is stabilized by the formation of strong H-bonding network with the coordinated water molecule. Removal and reabsorption of the water molecule have been studied by thermal analysis.
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