Transition metal-directed self-assembly of calix[4]arene based dithiocarbamate ligandsWebber, P.R.A., Drew, M.G.B., Hibbert, R. and Beer, P.D. (2004) Transition metal-directed self-assembly of calix[4]arene based dithiocarbamate ligands. Dalton Transactions (8). pp. 1127-1135. ISSN 1364-5447 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1039/b400929k Abstract/SummaryThe transition metal-directed self-assembly of dithiocarbamate ligand functionalised upper and lower rim calix[4]arenes affords novel dimeric bimetallic bis(calix[4]arene) species as determined by a combination of analytical methods including X-ray crystallography. An exception is a zinc(II) dithiocarbamate upper rim calix[4]arene assembly which is monomeric in nature. Electrochemical investigations reveal the bimetallic copper(II) bis(calix[4]arene) systems can electrochemically sense dihydrogen phosphate and carboxylate anions via significant cathodic perturbations of the respective copper(II)/(III) dithiocarbamate oxidation wave.
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