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Crystal structures of [PhLi center dot(-)-sparteine](2), [PhOLi center dot(-)-sparteine](2), and the mixed aggregate [PhLi center dot PhOLi center dot 2(-)-sparteine]

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Strohmann, C., Dilsky, S. and Strohfeldt, K. (2006) Crystal structures of [PhLi center dot(-)-sparteine](2), [PhOLi center dot(-)-sparteine](2), and the mixed aggregate [PhLi center dot PhOLi center dot 2(-)-sparteine]. Organometallics, 25 (1). pp. 41-44. ISSN 0276-7333

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To link to this item DOI: 10.1021/om050794w

Abstract/Summary

Crystal structure determination of adducts of sparteine and PhLi, (-)-sparteine and PhOLi and of sparteine and PhLi/PhOLi reveal a four-membered ring with two lithium centers, each capped by a (-)-sparteine ligand, as central motif of all structure. Quantum-chemical calculations show that the mixed aggregate [PhLi center dot PhOLi center dot 2(-)-sparteine] is energetically more favorable than the model system {1/2[PhLi center dot(-)-sparteine](2) + 1/2[PhOLi center dot(-)-sparteine](2)}.

Item Type:Article
Refereed:Yes
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > School of Pharmacy
ID Code:13627
Uncontrolled Keywords:ORGANOLITHIUM COMPOUNDS, N-BUTYLLITHIUM, ALKYL-LITHIUM, PHENYLLITHIUM, COMPLEXES, CHEMISTRY, ARYL, REACTIVITY, COMPOUND, ALKALI
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