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Dynamics of interacting edge defects in copolymer lamellae

McGraw, J. D., Rowe, I. D. W., Matsen, M. and Dalnoki-Veress, K. (2011) Dynamics of interacting edge defects in copolymer lamellae. European Physical Journal E, 34 (12). 131. ISSN 1292-8941

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To link to this item DOI: 10.1140/epje/i2011-11131-7


It is known that terraces at the air-polymer interface of lamella forming diblock copolymers do not make discontinuous jumps in height. Despite the underlying discretized structure, the height profiles are smoothly varying. The width of a transition region of a terrace edge in isolation is typically several hundreds of nanometres, resulting from a balance between surface tension, chain stretching penalties, and the enthalpy of mixing. What is less well known in these systems is what happens when two transition regions interact with one another. In this study, we investigate the dynamics of the interactions between copolymer lamellar edges. We find that the data can be well described by a model that assumes a repulsion between adjacent edges. While the model is simplistic, and does not include molecular level details, its agreement with the data suggest that some of the the underlying assumptions provide insight into the complex interplay between defects.

Item Type:Article
Divisions:Science > School of Mathematical, Physical and Computational Sciences > Department of Mathematics and Statistics
ID Code:25911

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