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A three-dimensional open-framework indium selenide: [C7H10N][In9Se14]

Vaqueiro, P. (2008) A three-dimensional open-framework indium selenide: [C7H10N][In9Se14]. Inorganic Chemistry, 47 (1). pp. 20-22. ISSN 0020-1669

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To link to this item DOI: 10.1021/ic701995p


An open-framework indium selenide, [C7H10N][In9Se14], has been prepared under solvothermal conditions in the presence of 3,5-dimethylpyridine, and characterized by single crystal diffraction, thermogravimetry, elemental analysis, FTIR spectroscopy and UV-Vis diffuse reflectance. The crystal structure of [C7H10N][In9Se14] contains an unusual building unit, in which corner-linked and edge-linked InSe45- tetrahedra coexist. The presence of one-dimensional circular channels, of ca. 6 Å diameter, results in approximately 25% of solvent accessible void space.

Item Type:Article
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:34234
Publisher:American Chemical Society


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