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Cation distribution and mixing thermodynamics in Fe/Ni thiospinels

Haider, S., Grau-Crespo, R. ORCID:, Devey, A. J. and de Leeuw, N. H. (2012) Cation distribution and mixing thermodynamics in Fe/Ni thiospinels. Geochimica Et Cosmochimica Acta, 88. pp. 275-282. ISSN 0016-7037

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To link to this item DOI: 10.1016/j.gca.2012.04.007


The structural analogy between Ni-doped greigite minerals (Fe3S4) and the (Fe,Ni)S clusters present in biological enzymes has led to suggestions that these minerals could have acted as catalysts for the origin of life. However, little is known about the distribution and stability of Ni dopants in the greigite structure. We present here a theoretical investigation of mixed thiospinels (Fe1

Item Type:Article
Divisions:No Reading authors. Back catalogue items
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:36083


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