Accessibility navigation


Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(II) in a square-planar environment

Chippindale, A. M. ORCID: https://orcid.org/0000-0002-5918-8701, Hibble, S. J., Marelli, E., Bilbe, E. J., Hannon, A. C. and Zbiri, M. (2015) Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(II) in a square-planar environment. Dalton Transactions, 44 (28). pp. 12502-12506. ISSN 1364-5447

[img]
Preview
Text - Accepted Version
· Please see our End User Agreement before downloading.

957kB

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1039/c5dt01127b

Abstract/Summary

Layered copper–nickel cyanide, CuNi(CN)4, a 2-D negative thermal expansion material, is one of a series of copper(II)-containing cyanides derived from Ni(CN)2. In CuNi(CN)4, unlike in Ni(CN)2, the cyanide groups are ordered generating square-planar Ni(CN)4 and Cu(NC)4 units. The adoption of square-planar geometry by Cu(II) in an extended solid is very unusual.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Optical Spectroscopy (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Thermal Analysis (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
ID Code:40776
Publisher:Royal Society of Chemistry

Downloads

Downloads per month over past year

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation