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A new class of hybrid super-supertetrahedral cluster and its assembly into a five-fold interpenetrating network

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Vaqueiro, P. ORCID: https://orcid.org/0000-0001-7545-6262, Makin, S., Tong, Y. and Ewing, S. J. (2017) A new class of hybrid super-supertetrahedral cluster and its assembly into a five-fold interpenetrating network. Dalton Transactions, 46 (12). pp. 3816-3819. ISSN 1364-5447

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To link to this item DOI: 10.1039/C7DT00280G

Abstract/Summary

We describe an entirely new type of tetrahedral cluster, representing a new level of structural hierarchy: a hybrid tetrahedron of supertetrahedra, formed by five T3 supertetrahedral clusters connected by bipyridyl linkers. Covalent assembly of these 37 Å super-supertetrahedra with smaller T3 clusters results in the formation of a two-dimensional covalent network which contains pores in the mesoporous range.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF)
Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Thermal Analysis (CAF)
Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
ID Code:69262
Publisher:Royal Society of Chemistry
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