Carbon suboxide: the infrared spectrum from 1800 to 2600 cm-1Fusina, L., Mills, I. and Guelachvili, G. (1980) Carbon suboxide: the infrared spectrum from 1800 to 2600 cm-1. Journal of Molecular Spectroscopy, 79 (1). pp. 101-122. ISSN 0022-2852 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/0022-2852(80)90296-9 Abstract/SummaryThe infrared spectrum of carbon suboxide has been recorded from 1800 to 2600 cm−1 at a resolution of 0.003 cm−1. About 7% of the ca. 40 000 lines observed have been assigned and analyzed, belonging to 36 different bands. Most of these are associated with the fundamental ν3, at 2289.80 cm−1, and the combination band ν2 + ν4, at 2386.61 cm−1, each of which give rise to a system of sum bands, difference bands, and hot bands involving the low-wave-number fundamental ν7 at 18 cm−1. A few other tentative assignments are made. The bands have been analyzed for vibrational and rotational constants.
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