Accessibility navigation

The microwave spectrum of thietan-2,2,4,4-d4

Sont, W. N., Wieser, H. and Mills, I. (1980) The microwave spectrum of thietan-2,2,4,4-d4. Molecular Physics, 41 (5). pp. 1981-1989. ISSN 1362-3028

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1080/00268978000103801


The microwave spectrum for thietan-2,2,4,4-d4 is analysed in six of its lowest puckering states and up to J = 25. The close lying pairs of states of vp = 0/1, 2/3 and 4/5 are treated with a vibration-rotation hamiltonian which includes an off-diagonal coupling term in vp. Additional corrections to this coupling term in higher powers of the angular momentum operator are derived and their importance for improving the fit of calculated to observed data is tested. The variation of the centrifugal distortion constants with vp follows the model of Creswell and Mills (1974, J. molec. Spectrosc., 52, 392). A value is determined for the derivative with respect to the puckering coordinate of the ac-component of the inverse moment of inertia tensor.

Item Type:Article
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7553
Publisher:Taylor & Francis

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation