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Overtone bandshapes and IVR: CH stretch overtones in CHCl3

Baggott, J. E., Clase, H. J. and Mills, I. (1986) Overtone bandshapes and IVR: CH stretch overtones in CHCl3. The Journal of Chemical Physics, 84. pp. 4193-4195. ISSN 0021-9606

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To link to this item DOI: 10.1063/1.450040


The intracavity photoacoustic dye laser spectrum of CHCl3 in the gas phase at 16 350 cm−1 is reported. The v=6–0 overtone of the CH stretch is observed, and found to exhibit a rotational band contour closely analogous to the v=1–0 fundamental. The implication of this result for intramolecular vibrational energy redistribution is discussed.

Item Type:Article
Divisions:Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:7558
Publisher:American Institute of Physics

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