Article

Ryalls, J. ORCID: https://orcid.org/0000-0003-2015-3605, Bromfield, L., Mullinger, N., Langford, B., Mofikoya, A., Pfrang, C., Nemitz, E., Blande, J. and Girling, R. ORCID: https://orcid.org/0000-0001-8816-8075 (2024) Diesel exhaust and ozone adversely affect pollinators and parasitoids within flying insect communities. Science of the Total Environment. ISSN 1879-1026 doi: https://doi.org/10.1016/j.scitotenv.2024.177802 (In Press)

Airey, M. W. ORCID: https://orcid.org/0000-0002-9784-0043, Harrison, R. G. ORCID: https://orcid.org/0000-0003-0693-347X, Aplin, K. L., Pfrang, C. and McGinness, B. (2024) Electrical effects on droplet behaviour. Journal of Physics: Conference Series, 2702. 012015. ISSN 1742-6588 doi: https://doi.org/10.1088/1742-6596/2702/1/012015

Touhami, D., Mofikoya, A. O., Girling, R. D. ORCID: https://orcid.org/0000-0001-8816-8075, Langford, B., Misztal, P. K. and Pfrang, C. (2024) Atmospheric degradation of ecologically important biogenic volatiles: investigating the ozonolysis of (E)-β-ocimene, isomers of α and β-farnesene, α-terpinene and 6-methyl-5-hepten-2-one, and their gas-phase products. Journal of Chemical Ecology. ISSN 1573-1561 doi: https://doi.org/10.1007/s10886-023-01467-6

Milsom, A. ORCID: https://orcid.org/0000-0003-3875-9015, Squires, A. M. ORCID: https://orcid.org/0000-0003-1396-467X, Brasnett, C. ORCID: https://orcid.org/0000-0001-9235-1673, Sharratt, W. N. ORCID: https://orcid.org/0000-0003-2148-8423, Seddon, A. M. ORCID: https://orcid.org/0000-0002-5794-8500 and Pfrang, C. ORCID: https://orcid.org/0000-0001-9023-5281 (2023) Acoustic levitation with polarising optical microscopy (AL-POM): water uptake in a nanostructured atmospheric aerosol proxy. Environmental Science: Atmospheres, 3 (11). pp. 1579-1686. ISSN 2634-3606 doi: https://doi.org/10.1039/d3ea00083d

Langford, B., Ryalls, J. W. M. ORCID: https://orcid.org/0000-0003-2015-3605, Mullinger, N. J., Hayden, P., Nemitz, E., Pfrang, C., Robins, A., Touhami, D., Bromfield, L. M. and Girling, R. D. ORCID: https://orcid.org/0000-0001-8816-8075 (2023) Mapping the effects of ozone pollution and mixing on floral odour plumes and their impact on plant-pollinator interactions. Environmental Pollution. 122336. ISSN 0269-7491 doi: https://doi.org/10.1016/j.envpol.2023.122336

Milsom, A. ORCID: https://orcid.org/0000-0003-3875-9015, Squires, A. M. ORCID: https://orcid.org/0000-0003-1396-467X, Ward, A. D. ORCID: https://orcid.org/0000-0001-6946-2391 and Pfrang, C. ORCID: https://orcid.org/0000-0001-9023-5281 (2023) Molecular self-organization in surfactant atmospheric aerosol proxies. Accounts of Chemical Research, 56 (19). pp. 2555-2568. ISSN 1520-4898 doi: https://doi.org/10.1021/acs.accounts.3c00194

Ryalls, J. ORCID: https://orcid.org/0000-0003-2015-3605, Langford, B., Mullinger, N., Bromfield, L., Nemitz, E., Pfrang, C. and Girling, R. ORCID: https://orcid.org/0000-0001-8816-8075 (2022) Anthropogenic air pollutants reduce insect-mediated pollination services. Environmental Pollution, 297. 118847. ISSN 0269-7491 doi: https://doi.org/10.1016/j.envpol.2022.118847

Ryalls, J. M. W. ORCID: https://orcid.org/0000-0003-2015-3605, Staton, T. ORCID: https://orcid.org/0000-0003-0597-0121, Mullinger, N. J., Bromfield, L. M., Langford, B., Pfrang, C., Nemitz, E., Blande, J. D. and Girling, R. D. ORCID: https://orcid.org/0000-0001-8816-8075 (2022) Ozone mitigates the adverse effects of diesel exhaust pollutants on ground-active invertebrates in wheat. Frontiers in ecology and evolution, 10. 833088. ISSN 2296-701X doi: https://doi.org/10.3389/fevo.2022.833088

Gubb, C., Blanusa, T., Griffiths, A. and Pfrang, C. (2022) Potted plants can remove the pollutant nitrogen dioxide indoors. Air Quality, Atmosphere & Health, 15. pp. 479-490. ISSN 1873-9318 doi: https://doi.org/10.1007/s11869-022-01171-6

Gubb, C., Blanusa, T., Griffiths, A. and Pfrang, C. (2019) Interaction between plant species and substrate type in the removal of CO2 indoors. Air Quality, Atmosphere & Health, 12 (10). pp. 1197-1206. ISSN 1873-9326 doi: https://doi.org/10.1007/s11869-019-00736-2

Gubb, C., Blanusa, T., Griffiths, A. and Pfrang, C. (2018) Can houseplants improve indoor air quality by removing CO2 and increasing relative humidity? Air Quality, Atmosphere & Health, 11 (10). pp. 1191-1201. ISSN 1873-9318 doi: https://doi.org/10.1007/s11869-018-0618-9

Sebastiani, F., Campbell, R. A., Rastogi, K. and Pfrang, C. (2018) Night-time oxidation of surfactants at the air–water interface: effects of chain length, head group and saturation. Atmospheric Chemistry and Physics, 18 (5). pp. 3249-3268. ISSN 1680-7316 doi: https://doi.org/10.5194/acp-18-3249-2018

Pfrang, C., Rastogi, K., Cabrera-Martinez, E. R., Seddon, A. M., Dicko, C., Labrador, A., Plivelic, T. C., Cowieson, N. and Squires, A. M. (2017) Complex three–dimensional self-assembly in proxies for atmospheric aerosols. Nature Communications, 8. 1724. ISSN 2041-1723 doi: https://doi.org/10.1038/s41467-017-01918-1

Skoda, M. W.A., Thomas, B., Hagreen, M., Sebastiani, F. and Pfrang, C. (2017) Simultaneous neutron reflectometry and infrared reflection absorption spectroscopy (IRRAS) study of mixed monolayer reactions at the air–water interface. RSC Advances, 7 (54). pp. 34208-34214. ISSN 2046-2069 doi: https://doi.org/10.1039/c7ra04900e

Becerra, R. and Pfrang, C. (2016) Kinetic studies of nitrate radicals: flash photolysis at 193 nm. International Journal of Chemical Kinetics, 48 (12). pp. 806-811. ISSN 1097-4601 doi: https://doi.org/10.1002/kin.21035

Seddon, A. M., Richardson, S. J., Rastogi, K., Plivelic, T. S., Squires, A. M. and Pfrang, C. (2016) Control of nanomaterial self-assembly in ultrasonically levitated droplets. Journal of Physical Chemistry Letters, 7 (7). pp. 1341-1345. ISSN 1948-7185 doi: https://doi.org/10.1021/acs.jpclett.6b00449

Sebastiani, F., Campbell, R. A. and Pfrang, C. (2015) Complementarity of neutron reflectometry and ellipsometry for the study of atmospheric reactions at the air–water interface. RSC Advances, 5 (129). pp. 107105-107111. ISSN 2046-2069 doi: https://doi.org/10.1039/c5ra22725a

Becerra, R., Cannady, J. P., Pfrang, C. and Walsh, R. (2015) Time-resolved gas-phase kinetic, quantum chemical and RRKM studies of the reaction of silylene with 2,5-dihydrofuran. Journal of Physical Chemistry A, 119 (46). pp. 11241-11253. ISSN 1089-5639 doi: https://doi.org/10.1021/acs.jpca.5b07404

Pfrang, C., Sebastiani, F., Lucas, C. O. M., King, M. D., Hoare, I. D., Chang, D. and Campbell, R. A. (2014) Ozonolysis of methyl oleate monolayers at the air–water interface: oxidation kinetics, reaction products and atmospheric implications. Physical Chemistry Chemical Physics, 16. pp. 13220-13228. ISSN 1463-9076 doi: https://doi.org/10.1039/c4cp00775a

Stewart, D. J., Almabrok, S. H., Lockhart, J. P., Mohamed, O. M., Nutt, D., Pfrang, C. and Marston, G. (2013) The kinetics of the gas-phase reactions of selected monoterpenes and cyclo-alkenes with ozone and the NO3 radical. Atmospheric Environment, 70. pp. 227-235. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2013.01.036

Shiraiwa, M., Pfrang, C., Koop, T. and Poschl, U. (2012) Kinetic multi-layer model of gas-particle interactions in aerosols and clouds (KM-GAP): linking condensation, evaporation and chemical reactions of organics, oxidants and water. Atmospheric Chemistry and Physics, 12 (5). pp. 2777-2794. ISSN 1680-7324 doi: https://doi.org/10.5194/acp-12-2777-2012

Shiraiwa, M., Pfrang, C., Koop, T. and Pöschl, U. (2011) Kinetic multi-layer model of gas-particle interactions in aerosols and clouds (KM-GAP): linking condensation, evaporation and chemical reactions of organics, oxidants and water. Atmospheric Chemistry and Physics Discussions, 11. pp. 33689-33732. ISSN 1680-7375 doi: https://doi.org/10.5194/acpd-11-33689-2011

Pfrang, C., Shiraiwa, M. and Pöschl, U. (2011) Chemical ageing and transformation of diffusivity in semi-solid multi-component organic aerosol particles. Atmospheric Chemistry and Physics, 11 (14). pp. 7343-7354. ISSN 1680-7324 doi: https://doi.org/10.5194/acp-11-7343-2011

Pfrang, C., Shiraiwa, M. and Pöschl, U. (2011) Chemical ageing and transformation of diffusivity in semi-solid multi-component organic aerosol particles. Atmospheric Chemistry and Physics Discussions, 11 (4). pp. 13003-13033. ISSN 1680-7375 doi: https://doi.org/10.5194/acpd-11-13003-2011

Thompson, K. , Rennie, A. , King, M. , Hardman, S. , Lucas, C. , Pfrang, C., Hughes, B. and Hughes, A. (2010) Reaction of a phospholipid monolayer with gas-phase ozone at the air-water interface: measurement of surface excess and surface pressure in real time. Langmuir, 26 (22). pp. 17295-17303. ISSN 0743-7463 doi: https://doi.org/10.1021/la1022714

Pfrang, C., Shiraiwa, M. and Pöschl, U. (2010) Coupling aerosol surface and bulk chemistry with a kinetic double layer model (K2-SUB): oxidation of oleic acid by ozone. Atmospheric Chemistry and Physics, 10 (10). pp. 4537-4557. ISSN 1680-7316 doi: https://doi.org/10.5194/acp-10-4537-2010

King, M. D., Rennie, A. R., Pfrang, C., Hughes, A. V. and Thompson, K. C. (2010) Interaction of nitrogen dioxide (NO2) with a monolayer of oleic acid at the air–water interface – A simple proxy for atmospheric aerosol. Atmospheric Environment, 44 (14). pp. 1822-1825. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2010.01.031

Shiraiwa, M., Pfrang, C. and Poschl, U. (2010) Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone. Atmospheric Chemistry and Physics, 10 (8). pp. 3673-3691. ISSN 1680-7316 doi: https://doi.org/10.5194/acp-10-3673-2010

Shiraiwa, M., Pfrang, C. and Poschl, U. (2010) Kinetic multi-layer model of aerosol surface and bulk chemistry (KM-SUB): the influence of interfacial transport and bulk diffusion on the oxidation of oleic acid by ozone. Atmospheric Chemistry and Physics Discussions, 10 (1). pp. 281-326. ISSN 1680-7375 doi: https://doi.org/10.5194/acpd-10-281-2010

King, M.D., Rennie, A.R., Thompson, K.C., Fisher, F.N., Dong, C.C., Thomas, R.K., Pfrang, C. and Hughes, A.V. (2009) Oxidation of oleic acid at the air-water interface and its potential effects on cloud critical supersaturations. Physical Chemistry Chemical Physics, 11 (35). pp. 7699-7707. ISSN 1463-9076 doi: https://doi.org/10.1039/b906517b

Pfrang, C., King, M.D., Braeckevelt, M., Canosa-Mas, C.E. and Wayne, R.P. (2008) Gas-phase rate coefficients for reactions of NO3, OH, O-3 and O(P-3) with unsaturated alcohols and ethers: correlations and structure-activity relations (SARs). Atmospheric Environment, 42 (13). pp. 3018-3034. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2007.12.046

King, M.D., Pfrang, C., Hughes, B.R., Thompson, K.C. and Ward, A.D. (2008) Oxidation of biogenic and water-soluble compounds in aqueous and organic aerosol droplets by ozone: a kinetic and product analysis approach using laser Raman tweezers. Faraday Discussions, 137. pp. 173-192. ISSN 1359-6640 doi: https://doi.org/10.1039/b702199b

Pfrang, C., King, M.D., Canosa-Mas, C.E., Flugge, M. and Wayne, R.P. (2007) Gas-phase rate coefficients for the reactions of NO3, OH and O-3 with alpha,beta-unsaturated esters and ketones: structure-activity relations (SARs). Atmospheric Environment, 41 (8). pp. 1792-1802. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2006.11.026

Pfrang, C., Baeza Romero, M. T., Cabanas, B., Canosa-Mas, C. E., Villanueva, F. and Wayne, R. P. (2007) Night-time tropospheric chemistry of the unsaturated alcohols (Z)-pent-2-en-1-ol and pent-1-en-3-ol: Kinetic studies of reactions of NO3 and N2O5 with stress-induced plant emissions. Atmospheric Environment, 41 (8). pp. 1652-1662. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2006.10.034

Pfrang, C., King, M.D., Canosa-Mas, C.E. and Wayne, R.P. (2006) Gas-phase rate coefficients for the reactions of O(3P), S(3P), Se(3P), and Te(3P) with alkenes: application of perturbation frontier molecular orbital theory, correlations, and structure-activity relations (SARs). International Journal of Chemical Kinetics, 38 (5). pp. 351-356. ISSN 1097-4601 doi: https://doi.org/10.1002/kin.20156

Pfrang, C., King, M., Canosa-Mas, C.E. and Wayne, R.P. (2006) Correlations for gas-phase reactions of NO3, OH and O3 with alkenes: an update. Atmospheric Environment, 40 (6). pp. 1170-1179. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2005.10.019

Pfrang, C., King, M.D., Canosa-Mas, C.E. and Wayne, R.P. (2006) Structure–activity relations (SARs) for gas-phase reactions of NO3, OH and O3 with alkenes: an update. Atmospheric Environment, 40 (6). pp. 1180-1186. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2005.09.080

Pfrang, C., Tooze, C., Nalty, A., Canosamas, C. and Wayne, R. (2006) Reactions of NO3 with the man-made emissions 2-methylpent-2-ene, (Z)-3-methylpent-2-ene, ethyl vinyl ether, and the stress-induced plant emission ethyl vinyl ketone. Atmospheric Environment, 40 (4). pp. 786-792. ISSN 1352-2310 doi: https://doi.org/10.1016/j.atmosenv.2005.10.009

Pfrang, C., Martin, R. S., Canosa-Mas, C. E. and Wayne, R. P. (2006) Gas-phase reactions of NO3 and N2O5 with (Z)-hex-4-en-1-ol, (Z)-hex-3-en-1-ol ('leaf alcohol'), (E)-hex-3-en-1-ol, (Z)-hex-2-en-1-ol and (E)-hex-2-en-1-ol. Physical Chemistry Chemical Physics, 8 (3). pp. 354-363. ISSN 1463-9076 doi: https://doi.org/10.1039/B510835G

Vaughan, S., Canosa-Mas, C. E., Pfrang, C., Shallcross, D. E., Watson, L. and Wayne, R.P. (2006) Kinetic studies of reactions of the nitrate radical (NO3) with peroxy radicals (RO2): an indirect source of OH at night? Physical Chemistry Chemical Physics, 8 (32). pp. 3749-3760. ISSN 1463-9076 doi: https://doi.org/10.1039/B605569A

Hollingsworth, A., Uppala, S., Klinker, E., Burridge, D., Vitart, F., Onvlee, J., De Vries, J. W., De Roo, A. and Pfrang, C. (2005) The transformation of earth-system observations into information of socio-economic value in GEOSS. Quarterly Journal of the Royal Meteorological Society, 131 (613). pp. 3493-3512. ISSN 1477-870X doi: https://doi.org/10.1256/qj.05.181

Pfrang, C., Martin, R. S., Nalty, A., Waring, R., Canosa-Mas, C. E. and Wayne, R. P. (2005) Gas-phase rate coefficients for the reactions of nitrate radicals with (Z)-pent-2-ene, (E)-pent-2-ene, (Z)-hex-2-ene, (E)-hex-2-ene, (Z)-hex-3-ene, (E)-hex-3-ene and (E)-3-methylpent-2-ene at room temperature. Physical Chemistry Chemical Physics, 7 (12). pp. 2506-2512. ISSN 1463-9076 doi: https://doi.org/10.1039/B502928G

Kasyutich, V.L., Canosa-Mas, C.E., Pfrang, C. and Vaughan, S. (2003) Cavity-enhanced absorption: detection of nitrogen dioxide and iodine monoxide using a violet laser diode. Applied Physics B - Lasers and Optics, 76 (6). pp. 691-697. ISSN 1432-0649 doi: https://doi.org/10.1007/s00340-003-1153-3

Kasyutich, V. L. , Canosa-Mas, C. E., Pfrang, C., Vaughan, S. and Wayne, R. P. (2002) Off-axis continuous-wave cavity-enhanced absorption spectroscopy of narrow-band and broadband absorbers using red diode lasers. Applied Physics B - Lasers and Optics, 75 (6-7). pp. 755-761. ISSN 1432-0649 doi: https://doi.org/10.1007/s00340-002-1032-3

Report

Pfrang, C., King, M.D. and Hunt, O.R., (2009) Exploring NOy chemistry in levitated aqueous aerosol droplets. Central Laser Facility. Report. Rutherford Appleton Laboratory, Harwell.