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Industrial radioactive barite scale: suppression of radium uptake by introduction of competing ions

Ceccarello, S., Black, S., Read, D. and Hodson, M. E. (2004) Industrial radioactive barite scale: suppression of radium uptake by introduction of competing ions. MINERALS ENGINEERING , 17 (2). pp. 323-330. ISSN 0892-6875

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To link to this item DOI: 10.1016/j.mineng.2003.11.007

Abstract/Summary

Incorporation of radioactive isotopes during the formation of barite mineral scale is a widespread phenomenon occurring within the oil, mining and process industries. In a series of experiments radioactive barite/celestite solid solutions (SSBarite-Celcstite) have been synthesized under controlled conditions by the counter diffusion of Ra-226, Ba2+, Sr24+ and SO42- ions through a porous medium (silica gel), to investigate inhibiting effects in Ra uptake associated with the introduction of a competing ion (Sr2+). From characterization studies, the particle size and the morphology of the crystals appear to be related to the initial [Sr]/[Ba] molar ratio of the starting solution. Typically, systems richer in Sr produce smaller sized crystals and clusters characterized by a lower degree of order. The activity introduced to the system is mainly incorporated in the crystals generated from the barite/celestite solid solution as suggested by the activity profiles of the hydrogel columns analysed by gamma-spectrometry. There is a relationship between the initial [Sr]/[Ba] molar ratio of the starting solution and the activity exhibited by the synthesized crystals. An effective inhibition of the Ra-226 uptake during formation of the crystals (SSBarite-Celestite) was obtained through the introduction of a competing ion (Sr2+): the higher the initial [Sr]/[Ba] molar ratio of the starting solution, the lower the intensity of the activity peak in the crystals. (C) 2003 Published by Elsevier Ltd.

Item Type:Article
Divisions:Faculty of Science > School of Archaeology, Geography and Environmental Science > Department of Geography and Environmental Science
Faculty of Science > School of Archaeology, Geography and Environmental Science > Department of Archaeology
Faculty of Science > School of Archaeology, Geography and Environmental Science > Scientific Archaeology
Faculty of Science > School of Archaeology, Geography and Environmental Science > Earth Systems Science
Interdisciplinary centres and themes > Soil Research Centre
ID Code:3369
Uncontrolled Keywords:mineral processing simulation environmental
Additional Information: Conference Information: Meeting on Processing and Disposal of Minerals Industry Wastes 2003 FALMOUTH, ENGLAND, JUN, 2003

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