The two-dimensional anharmonic oscillator II: the microwave spectrum of silyl isocyanate, SiH3NCODuckett, J. A., Robiette, A. G. and Mills, I. (1976) The two-dimensional anharmonic oscillator II: the microwave spectrum of silyl isocyanate, SiH3NCO. Journal of Molecular Spectroscopy, 62 (1). pp. 34-52. ISSN 0022-2852 Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/0022-2852(76)90260-5 Abstract/SummaryThe J + 1 ← J transitions (J = 2, 3, 4, 5, and 6) in the microwave spectrum of SiH3NCO have been assigned for the vibrational ground state and for the vibrational states v10 = 1, 2, and 3. The results for v10 = 0 confirm earlier work. The vibration-rotation constants show a remarkable variation with v10 and l10. To a large extent the anomalous behavior of these constants has been explained in terms of a strongly anharmonic potential function for the ν10 vibrational mode.
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