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Structural transformation of graphite by arc-discharge

Harris, P. J. F. (2011) Structural transformation of graphite by arc-discharge. Philosophical Magazine, 91 (18). pp. 2355-2363. ISSN 1478-6443

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To link to this item DOI: 10.1080/14786435.2011.562250


The formation of novel structures by the passage of an electric current through graphite is described. These structures apparently consist of hollow three-dimensional graphitic shells bounded by curved and faceted planes, typically made up of two graphene layers. The curved structures were frequently decorated with nano-scale carbon particles, or short nanotubes. In some cases, nanotubes were found to be seamlessly connected to the thin shells, indicating that the formation of the shells and the nanotubes is intimately connected. Small nanotubes or nanoparticles were also sometimes found encapsulated inside the hollow structures, while fullerene-like particles were often seen attached to the outside surfaces. With their high surface areas and structural perfection, the new carbon structures may have applications as anodes of lithium ion batteries or as components of composite materials.

Item Type:Article
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Electron Microscopy Laboratory (CAF)
ID Code:24740
Uncontrolled Keywords:graphene; carbon; graphite; carbon nanotube; fullerene
Publisher:Taylor & Francis


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