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Solid-state interconversions of coordination networks and hydrogen-bonded salts

Adams, C.J., Colquhoun, H.M., Crawford, P.C., Lusi, M. and Orpen, A.G. (2007) Solid-state interconversions of coordination networks and hydrogen-bonded salts. Angewandte Chemie-International Edition, 46 (7). pp. 1124-1128. ISSN 1433-7851

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To link to this item DOI: 10.1002/anie.200603593


Thermal or chemical treatment of crystalline 4,4-bipyridinium salts of [MCl4]2- (M=Co, Zn, Fe, or Pt) leads to HCl loss and formation of coordination network solids [{MCl2(4,4-bipy)}n]. For M=Co, Zn, and Fe, these solids can also be prepared by mechanochemical means. Their exposure to HCl vapor or the mechanochemical reaction of metal dichlorides with [4,4-H2bipy]Cl2 gives [4,4-H2bipy]2+ salts of [CoCl4]2-, [ZnCl4]2-, and, for the first time, [FeCl4]2-.

Item Type:Article
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:10954
Uncontrolled Keywords:complex salts, coordination networks, crystal engineering, crystal, growth, materials synthesis, METAL-ORGANIC FRAMEWORK, MECHANOCHEMICAL PREPARATION, SUPRAMOLECULAR, SYNTHONS, CRYSTAL-STRUCTURES, CO-CRYSTALS, POLYMERS, SOLVENT, POLYMORPH, DESIGN, CHAINS

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