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Surface modification of nylon 6,6 using a carbene insertion approach

Blencowe, A., Cosstick, K. and Hayes, W. (2006) Surface modification of nylon 6,6 using a carbene insertion approach. New Journal of Chemistry, 30 (1). pp. 53-58. ISSN 1144-0546

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To link to this article DOI: 10.1039/b514205a

Abstract/Summary

The diazirine functionalised fluorenone, 3-[3-(trifluoromethyl)diazirin-3-yl]phenyl-9-oxo-9H-fluorene-2-carboxyla te was synthesised to act as a model compound capable of modifying a wide variety of polymeric substrates. Photochemical activation of the diazirine moiety of the fluorenone derivative was utilised to afford highly reactive carbenes capable of insertion into or addition to a wide variety of functionalities. In this paper the photoinduced attachment of a fluorenone derivative to nylon 6,6 has been studied using UV-visible spectroscopic analysis. Incorporation of the fluorenone chromophore onto the backbone of nylon at different loading levels and after different coating cycles has been investigated and is detailed in this paper.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11038
Uncontrolled Keywords:AROMATIC-SUBSTITUTION, AMINES, DYES, DECOMPOSITION, SPECTROSCOPY, CARBOCATIONS, DISPERSE, REAGENT, ACIDS

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