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Gas-phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene

Boganov, S.E., Egorov, M.P., Faustov, V.I., Krylova, I.V., Nefedov, O.M., Becerra, R. and Walsh, R. (2005) Gas-phase kinetic and theoretical studies of reactions of germylenes and dimethylstannylene. Russian Chemical Bulletin, 54 (3). pp. 483-511. ISSN 1066-5285

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To link to this item DOI: 10.1007/s11172-005-0285-5

Abstract/Summary

The results of time-resolved gas phase studies of labile germylenes (GeH2 and GeMe2) and dimethylstannylene (SnMe2) reactions reported to date are considered together with data of quantum-chemical investigations of the potential energy surfaces of these systems. Reaction mechanisms are discussed. A comparison of reactivity in the series of carbene analogs, ER2 (E = Si, Ge, Sn, R = H, Me), is made.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11042
Uncontrolled Keywords:germylene, dimethylgermylene, dimethylstannylene, reaction kinetics, time-resolved, studies, quantum-chemical calculations, RRKM calculations, Arrhenius parameters, thermochemistry, ABSOLUTE RATE CONSTANTS, LASER FLASH-PHOTOLYSIS, QUANTUM-CHEMICAL CALCULATIONS, SILYLENE ADDITION-REACTION, POTENTIAL-ENERGY SURFACE, ARYL-SUBSTITUTED TRIGERMANES, H INSERTION REACTION, TEMPERATURE-DEPENDENCE, AB-INITIO, THERMAL-DECOMPOSITION

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