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Unexpectedly superior enantioselectivity for trans-stilbene cis-dihydroxylation over anchored triosmium carbonyl species in confined Al-MCM-41 channels

Caps, V., Paraskevas, I. and Tsang, S.C. (2005) Unexpectedly superior enantioselectivity for trans-stilbene cis-dihydroxylation over anchored triosmium carbonyl species in confined Al-MCM-41 channels. Chemical Communications, 2005 (13). pp. 1781-1783. ISSN 1359-7345

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To link to this item DOI: 10.1039/b417787h

Abstract/Summary

Superior enantioselectivity in the dihydroxylation of trans-stilbene catalysed by anchored triosmium carbonyl species without using a chiral modifier is observed inside sterically congested MCM-41 channels; this effect is more pronounced through the introduction of surface Al sites into the silicate.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11076
Uncontrolled Keywords:CATALYTIC ASYMMETRIC DIHYDROXYLATION, OLEFINS, SILICA, MCM-41

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