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The first metamagnetic thiocyanato-bridged one-dimensional nickel(II) complex

Chattopadhyay, S., Drew, M.G.B., Diaz, C. and Ghosh, A. (2007) The first metamagnetic thiocyanato-bridged one-dimensional nickel(II) complex. Dalton Transactions (24). pp. 2492-2494. ISSN 1364-5447

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To link to this item DOI: 10.1039/b702814h

Abstract/Summary

A novel single thiocyanato- bridged one- dimensional polymer, [NiL(NCS)(mu-NCS)](n) (L = N-1-(1-pyridin-2-yl-ethylidine)propane-1,3-diamine) has been synthesized and characterized by X-ray crystallography and a variable temperature magnetic study; the compound is a metamagnet with a Neel temperature (T-N) of 3.5 K.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11120
Uncontrolled Keywords:MAGNETIC-PROPERTIES, CRYSTAL-STRUCTURE, DINUCLEAR COMPLEXES, CIS, POSITION, AZIDO, EXCHANGE, BEHAVIOR, LIGANDS, DIMERS
Publisher:Royal Society of Chemistry

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