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Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti-III/Ti-IV

Chippindale, A.M., Grimshaw, M.R., Powell, A.V. and Cowley, A.R. (2005) Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti-III/Ti-IV. Inorganic Chemistry, 44 (12). pp. 4121-4123. ISSN 0020-1669

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To link to this item DOI: 10.1021/ic050399y

Abstract/Summary

The first 3-D open-framework TiGaPO complex, constructed from (TiO6)-O-III, (TiO6)-O-IV, GaO4, and PO4 polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure.

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11131
Uncontrolled Keywords:GALLIUM PHOSPHATE, HYDROTHERMAL SYNTHESIS, GISMONDINE, TOPOLOGY, ANALOG

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