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Simple linear asymmetrical complexes of silver(I): NC-Ag-NH3 and Br-Ag-NH3

Chippindale, A.M., Head, L.E. and Hibble, S.J. (2008) Simple linear asymmetrical complexes of silver(I): NC-Ag-NH3 and Br-Ag-NH3. Chemical Communications (26). pp. 3010-3012. ISSN 1359-7345

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To link to this item DOI: 10.1039/b803500h

Abstract/Summary

The compounds Ag(CN)(NH3) and Ag(Br)(NH3) are remarkable in that they form solids containing the simple molecular units NC-Ag-NH3 and Br-Ag-NH3, rather than extended solids, and are the first examples of simple linear asymmetric complexes of silver(I).

Item Type:Article
Refereed:Yes
Divisions:Interdisciplinary centres and themes > Chemical Analysis Facility (CAF) > Xray (CAF)
Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11132
Uncontrolled Keywords:UNSUPPORTED ARGENTOPHILIC INTERACTIONS, CRYSTAL-STRUCTURE, ADDUCTS, CYANIDE, LIGAND, SPECTROSCOPY, BASES

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