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The oxadiazolyldiazenido(1-) ligand: a remarkably versatile platform for the synthesis of heteropolynuclear transition metal complexes

Colquhoun, H.M., Chan, Y.F., Cardin, C.J., Drew, M.G.B., Gan, Y., El Kader, K.A. and White, T.M. (2007) The oxadiazolyldiazenido(1-) ligand: a remarkably versatile platform for the synthesis of heteropolynuclear transition metal complexes. Dalton Transactions (35). pp. 3864-3867. ISSN 1364-5447

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To link to this article DOI: 10.1039/b711166p

Abstract/Summary

Cyclo-condensation of aroyl hydrazides with the cationic tungsten-dichlorodiazomethane complex [BrW(dppe)(2)(N2CCI2)](+) affords neutral oxadiazolyldiazenido(1-) complexes which react readily with a wide range of transition and non-transition metal species to afford a novel series of crystallographically-characterised heteropolynuclear complexes containing bridging oxadiazolyldiazenido(1-) ligands.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11145
Uncontrolled Keywords:MOLECULAR-STRUCTURES, MULTIPLE BONDS, ASSEMBLIES, POLYMERS, CRYSTAL, CENTERS, BRIDGES, ATOMS
Publisher:Royal Society of Chemistry

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