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A novel cation induced polymeric chain in Na-8[{Cu(gly)(2)}(2)]{H-2(H2W12O42)}] center dot 24H(2)O: hydrothermal synthesis, spectroscopic characterization and X-ray structure analysis

Dutta, D., Maity, D., Ali, M., Drew, M.G.B., Mondal, S. and Mukherjee, M. (2008) A novel cation induced polymeric chain in Na-8[{Cu(gly)(2)}(2)]{H-2(H2W12O42)}] center dot 24H(2)O: hydrothermal synthesis, spectroscopic characterization and X-ray structure analysis. Transition Metal Chemistry, 33 (3). pp. 347-351. ISSN 0340-4285

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To link to this item DOI: 10.1007/s11243-007-9049-4

Abstract/Summary

A novel bis(glycinato) copper(II) paradodecatungstate Na-8[{Cu(gly)(2)}(2)]-{H-2(H2W12O42)}] center dot 24H(2)O (1) has been synthesized under hydrothermal conditions. The crystal structure of 1 reveals an infinite one-dimensional chain along the [100] direction and is built from paradodecatungstate (H2W12O42)(10-) clusters joined through [Cu(gly)(2)] moieties. Parallel chains are interlinked by NaO6 octahedra to generate a two-dimensional network.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11240
Uncontrolled Keywords:CRYSTAL-STRUCTURE, COMPLEXES, PARADODECATUNGSTATE, HYBRID, PARATUNGSTATE, CLUSTERS

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