Polymer-supported nitroxyl catalysts for selective oxidation of alcohols
Ferreira, P., Hayes, W., Phillips, E., Rippon, D. and Tsang, S.C. (2004) Polymer-supported nitroxyl catalysts for selective oxidation of alcohols. Green Chemistry, 6 (7). pp. 310-312. ISSN 1463-9262
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To link to this article DOI: 10.1039/b406829g
Novel non-toxic poly(ethylene glycol)-supported 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) moieties are demonstrated to give an excellent interfacial catalysis for the selective oxidation of alcohols to the corresponding carbonyl species in biphasic media and investigation for the recovery of these new macromolecular catalysts via precipitation with diethyl ether after catalysis has also been briefly studied.