Accessibility navigation


Synthesis and catalytic epoxidation potentiality of oxodiperoxo molybdenum(VI) complexes with pyridine-2-carboxaldoxime and pyridine-2-carboxylate: the crystal structure of PMePh3[MoO(O-2)(2)(PyCO)]

Gharah, N., Drew, M. G. B. and Bhattacharyya, R. (2009) Synthesis and catalytic epoxidation potentiality of oxodiperoxo molybdenum(VI) complexes with pyridine-2-carboxaldoxime and pyridine-2-carboxylate: the crystal structure of PMePh3[MoO(O-2)(2)(PyCO)]. Transition Metal Chemistry, 34 (5). pp. 549-557. ISSN 0340-4285

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1007/s11243-009-9228-6

Abstract/Summary

[MoO(O-2)(2)(PyCOXH)(H2O)] and PMePh3[MoO(O-2)(2)(PyCO)] (PyCOXH = Pyridine-2-carboxaldoxime and PyCOH = Pyridine-2-carboxylic acid) have been synthesized. Both complexes have been characterized by physico-chemical and spectroscopic methods; in addition, the carboxylate complex has been structurally characterized by X-ray crystallography. The carboxylate complex is a more efficient catalyst than the oxime complex for epoxidation of olefins and shows excellent catalytic activity for the substrates: cyclooctene, cinnamyl alcohol, allyl alcohol and 1-hexene.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11268
Uncontrolled Keywords:HIGHLY EFFICIENT EPOXIDATION, ELECTRON-DEFICIENT OLEFINS, HYDROGEN-PEROXIDE, TERMINAL OXIDANT, AQUEOUS H2O2, OXIDATION, ALCOHOLS, BICARBONATE, SULFIDES, BENIGN

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation