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Unusual transformation of trialkylamines mediated by platinum

Halder, S., Drew, M.G.B. and Bhattacharya, S. (2006) Unusual transformation of trialkylamines mediated by platinum. Organometallics, 25 (26). pp. 5969-5972. ISSN 0276-7333

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To link to this item DOI: 10.1021/om0607494

Abstract/Summary

An interesting chemical transformation of trialkylamines has taken place during the reaction of 2-(2', 6'-dimethylphenylazo)- 4-methylphenol ( 1) with K-2[ PtCl4] in refluxing methanol in the presence of trialkylamines, leading to the formation of organoplatinum complexes ( 2 and 3), where ligand 1 is coordinated as a bidentate N, O donor and the transformed trialkylamines are coordinated as bidentate C, N donors.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11301
Uncontrolled Keywords:H BOND ACTIVATION, C-C, ALPHA-ALKENYLPHOSPHINE, REDOX PROPERTIES, METHYL-GROUP, COMPLEXES, OSMIUM, 2-(ARYLAZO)PHENOLS, RUTHENIUM, CHEMISTRY

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