Accessibility navigation


The chemistry of intrinsically chiral surfaces

Held, G. and Gladys, M.J. (2008) The chemistry of intrinsically chiral surfaces. Topics in Catalysis, 48 (1-4). pp. 128-136. ISSN 1022-5528

Full text not archived in this repository.

To link to this article DOI: 10.1007/s11244-008-9050-y

Abstract/Summary

Intrinsically chiral metal and mineral surfaces show enantioselective behaviour without modifiers. Examples are artificial high-Miller-index surfaces of metal single crystals with cubic bulk lattice symmetry, which have no mirror planes and are therefore chiral, or surfaces of naturally occurring crystallites of some common minerals, such as alpha-quartz or calcite. Recent findings with regards to the surface geometry, reactivity and thermal stability of intrinsically chiral surfaces are discussed. A number of enantioselective effects have been reported in connection with the adsorption of small chiral molecules (e.g. alanine, cysteine) on intrinsically chiral surfaces under well-defined conditions. From a combination of experimental surface science techniques and theoretical ab initio model calculations it emerges that these effects are due to a combination of attractive and repulsive adsorbate-substrate and inter-adsorbate interactions.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11326
Uncontrolled Keywords:enantioselective effects, model calculations , ENANTIOSELECTIVE HETEROGENEOUS CATALYSIS, SCANNING-TUNNELING-MICROSCOPY, RACEMIC ALANINE ADLAYERS, METAL-SURFACES, ENANTIOSPECIFIC ADSORPTION, CRYSTALLINE SURFACES, ELECTRONIC-STRUCTURE, PLATINUM SURFACES, ORGANIC-MOLECULES, PROPYLENE-OXIDE

Centaur Editors: Update this record

Page navigation