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Complexes of the uranyl ion with bis(diphenylphosphino)methane dioxide

Kannan, S., Rajalakshmi, N., Chetty, K.V., Venugopal, V. and Drew, M.G.B. (2004) Complexes of the uranyl ion with bis(diphenylphosphino)methane dioxide. Polyhedron, 23 (9). pp. 1527-1533. ISSN 0277-5387

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To link to this item DOI: 10.1016/j.poly.2004.03.008

Abstract/Summary

Bis(diphenylphosphino)methane dioxide compounds of uranyl nitrate and uranyl bis(beta-diketonates) have been synthesized and characterized by spectroscopic and X-ray diffraction methods. Monodentate, bidentate chelate and bridging bidentate modes of coordination for this ligand have been established from the single-crystal X-ray diffraction studies of its compounds, [UO2(DBM)(2)DPPMO], [UO2(NO3)(2)DPPNO] and [{UO2(DBM)(2)}(2)DPPMO], respectively. (C) 2004 Elsevier Ltd. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11383
Uncontrolled Keywords:bis(diphenylphosphino)methane dioxide, uranyl nitrate, uranyl bis(beta-diketonates), monodentate, bidentate chelate, bridging bidentate, coordination modes , MOLECULAR-STRUCTURE, COORDINATION CHEMISTRY, CRYSTAL-STRUCTURES, OXIDE LIGANDS, THORIUM NITRATE, DIPHOSPHINE, EXTRACTION, BIS-(DISUBSTITUTEDPHOSPHINYL)-ALKANES, ACTINIDE, DIARSINE

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