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A novel trinuclear nickel(II) complex of an unsymmetrical tetradentate ligand involving bridging oxime and acetylacetone functions

Maity, D., Mukherjee, P., Ghosh, A., Drew, M. G. B. and Mukhopadhyay, G. (2008) A novel trinuclear nickel(II) complex of an unsymmetrical tetradentate ligand involving bridging oxime and acetylacetone functions. Inorganica Chimica Acta, 361 (5). pp. 1515-1519. ISSN 0020-1693

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To link to this item DOI: 10.1016/j.ica.2007.08.014

Abstract/Summary

A novel trinuclear nickel(II) complex, [Ni-3(L)(2)(H2O)(2)](ClO4)(2), where L is a bridging unsymmetrical tetradentate ligand, involving o-phenylenediamine, diacetyl monoxime and acetylacetone (H2L = 4-[2-(3-hydroxy-1-methyl-but-2-enylideneamino)-phenylimino]-pentan-2- one oxime) has been synthesized and characterized structurally. In the complex, an octahedral Ni( II) centre is held in the middle by two square planar units with the aid of oxime and ketonic bridges. (c) 2007 Elsevier B. V. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11452
Uncontrolled Keywords:trinuclear Ni(II), unsymmetrical ligand, oxime bridge, ketonic bridge, crystal structure, SCHIFF-BASE COMPLEXES, MAGNETIC-PROPERTIES, COPPER(II) COMPLEXES, METAL-COMPLEXES, CENTERS, CU, PRECURSORS, CHEMISTRY, SALEN, NI

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