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2D parallel interpenetration of [M-2(bpp)(4)X-4] [M, Fe(II)/Co(II); bpp, 4,4 '-trimethylenedipyridine; X, SCN-SeCN- and N-3(-)] complexes: pseudohalide-dependent conformation of bpp

Manna, S.C., Jana, A.D., Rosair, G.M., Drew, M.G.B., Mostafa, G. and Chaudhuri, N.R. (2008) 2D parallel interpenetration of [M-2(bpp)(4)X-4] [M, Fe(II)/Co(II); bpp, 4,4 '-trimethylenedipyridine; X, SCN-SeCN- and N-3(-)] complexes: pseudohalide-dependent conformation of bpp. Journal of Solid State Chemistry, 181 (3). pp. 457-466. ISSN 0022-4596

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To link to this item DOI: 10.1016/j.jssc.2007.12.009

Abstract/Summary

Three coordination complexes of Co(II)/Fe(II) with 4,4'-trimethylenedipyridine (bpp) and pseudohalides (SCN-, SeCN- and N-3(-)) have been synthesized. The complexes have been characterized by X-ray single crystal structure determination. They are isomorphous having 2D layers in which two independent wavy nets display parallel interwoven structures. Pseudohalide binds metal centers through N terminal and occupies the trans axial positions of the octahedral metal coordination environment. Pseudohalide remains pendant on both sides of the polymeric layer and help the stacking through hydrogen bonding. The conformation of bpp in the interpenetrated nets is observed to be dependent on the choice of pseudohalide. (C) 2008 Elsevier Inc. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11459
Uncontrolled Keywords:4, 4'-trimethylenedipyridine, Fe(II), Co(II), pseudohalide, interpenetration, supramolecule , METAL-ORGANIC FRAMEWORK, INORGANIC 3D NETWORKS, COORDINATION POLYMERS, CRYSTAL-STRUCTURE, LIGAND, SOLIDS, CADMIUM(II), COPPER(II), CHEMISTRY, DATABASE

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