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Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex

Smith, M.E., Flynn, E.L., Fox, M.A., Trottier, A., Wrede, E., Yufit, D.S., Howard, J.A.K., Ronayne, K.L., Towrie, M., Parker, A.W., Hartl, F. and Low, P.J. (2008) Facile photoinduced charge separation through a cyanoacetylide bridge in a heterobimetallic Fe(II)-Re(I) complex. Chemical Communications (44). pp. 5845-5847. ISSN 1359-7345

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To link to this article DOI: 10.1039/b811357b

Abstract/Summary

Photoinduced Fe-to-bpy charge transfer in [{Cp(dppe)Fe}-(mu-C CC N){Re(CO)(3)(bpy)}]PF6 has been observed by ps-TRIR spectroscopy, supported by UV-Vis/IR spectroelectrochemistry and DFT calculations.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11625
Uncontrolled Keywords:EXCITED-STATE, ELECTROCHEMICAL PROPERTIES, METAL-COMPLEXES, BEHAVIOR, LIGANDS, SPECTROSCOPY, CHEMISTRY

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