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Synthesis and crystal structure of [(BU4N)-B-n][Er(pic)(4)] center dot 5.5H(2)O: a new infrared emitter

Soares-Santos, P.C.R., Nogueira, H.I.S., Felix, V., Drew, M.G.B., Ferreira, R.A.S., Carlos, L.D. and Trindade, T. (2003) Synthesis and crystal structure of [(BU4N)-B-n][Er(pic)(4)] center dot 5.5H(2)O: a new infrared emitter. Inorganic Chemistry Communications, 6 (9). pp. 1234-1238. ISSN 1387-7003

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To link to this item DOI: 10.1016/S1387-7003(03)00239-9

Abstract/Summary

The new erbium(III) complex of picolinic acid (Hpic), ["Bu4N][Er(pic)(4)].5.5H(2)O, was synthesized and the crystal structure determined by single-crystal X-ray diffraction. The compound was further characterized using IR, Raman, H-1 NMR and elemental analysis. The picolinate ligands (pic(-)) are coordinated through N,O-chelation to the erbium cations, as shown by X-ray diffraction and spectroscopic results, leading to an eight coordinate complex. Photoluminescence measurements were performed for this compound which exhibits infrared emission. (C) 2003 Elsevier B.V. All rights reserved.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11629
Uncontrolled Keywords:erbium complexes, picolinic acid, crystal structure, photoluminescence , ALPHA-PICOLINIC ACIDS, LN-N BONDS, SILVER SOL, COMPLEXES, SPECTROSCOPY, HEXAHYDRATE, LANTHANIDES, OXIDE

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