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A phosphorus analogue of Bis(eta(4)-cyclobutadiene)iron(0)

Wolf, R., Slootweg, J.C., Ehlers, A.W., Hartl, F., de Bruin, B., Lutz, M., Spek, A.L. and Lammertsma, K. (2009) A phosphorus analogue of Bis(eta(4)-cyclobutadiene)iron(0). Angewandte Chemie-International Edition, 48 (17). pp. 3104-3107. ISSN 1433-7851

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To link to this article DOI: 10.1002/anie.200805193

Abstract/Summary

P makes it possible: The convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(4-P2C2tBu2)2] suggests that the elusive all-carbon complex [Fe(4-C4H4)2] is a viable synthetic target.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:11708
Uncontrolled Keywords:cyclobutadiene ligands, density functional calculations, iron, phosphorus, sandwich complexes , TRANSITION-METAL-COMPLEXES, IRON COMPLEXES, TRICARBONYL, CHEMISTRY, CYCLOBUTADIENE, COORDINATION, REACTIVITY, ANION

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