Syntheses, structures, some reactions, and electrochemical oxidation of ferrocenylethynyl complexes of iron, ruthenium, and osmiumTools  Bruce, M. I., Low, P. J., Hartl, F., Humphrey, P. A., de Montigny, F., Jevric, M., Lapinte, C., Perkins, G. J., Roberts, R. L., Skelton, B. W. and White, A. H. (2005) Syntheses, structures, some reactions, and electrochemical oxidation of ferrocenylethynyl complexes of iron, ruthenium, and osmium. Organometallics, 24 (22). pp. 5241-5255. ISSN 1520-6041 Full text not archived in this repository. To link to this article DOI: 10.1021/om050483l Abstract/SummaryThe syntheses and characterizations of several complexes containing ferrocenylethynyl and ferrocene-1,1'-bis(ethynyl) groups attached to M(PP)Cp'[M = Fe, Ru, PP = dppe, Cp'= Cp*; M = Ru, Os, PP = (PPh3)(2), dppe, Cp' = Cp] are described. Reactions with tetracyanoethene have given either tetracyanobuta-1,3-dienyl or eta(3)-allylic derivatives, while addition of Me+ afforded the corresponding vinylidene derivatives. Some electrochemical measurements are discussed in terms of electronic communication between the redox-active M(PP)Cp' groups through the ferrocene nucleus. The molecular structures of 14 of these complexes have been determined by crystallographic methods.
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