[Pr(NO3)3L]: a mononuclear ten-coordinate lanthanide(III) complex with a tetradentate di-Schiff base
Gourbatsis, S., Plakatouras, J. C., Nastopoulos, V., Cardin, C. and Hadjiliadis, N. (1999) [Pr(NO3)3L]: a mononuclear ten-coordinate lanthanide(III) complex with a tetradentate di-Schiff base. Inorganic Chemistry Communications, 2 (10). pp. 468-471. ISSN 1387-7003
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To link to this article DOI: 10.1016/S1387-7003(99)00126-4
The novel praseodymium(III) complex [Pr(NO3)3L] (1), where L=N,N′-bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine, has been obtained by direct reaction of the Schiff base and the metal salt; the gadolinium(III) homologue has also been prepared and so far characterized only spectroscopically. The crystal structure resembles those reported for hexadentate macrocyclic Schiff bases.