Reactions of methylvinyl and phenylvinyl ketones with a tricyclic ketone derived from 2-tetralone: characterization of crystalline products by X-ray diffractionTools  Cardin, C. J., Carson, M. S., Cocker, W., Wilcock, D. J. and Shannon, P. V. R. (1993) Reactions of methylvinyl and phenylvinyl ketones with a tricyclic ketone derived from 2-tetralone: characterization of crystalline products by X-ray diffraction. Tetrahedron, 49 (34). pp. 7487-7498. ISSN 0040-4020 Full text not archived in this repository. To link to this article DOI: 10.1016/S0040-4020(01)87225-2 Abstract/SummaryBase catalysed reaction of the tricyclic ketone (6 ⇌ 7) with methylvinyl ketone gave the tetracyclic ketols, 11, 13, 15, 16, and the pentacyclic ketols, 12, 17. With phenylvinyl ketone, the tetracyclic ketol (18) was formed. The stereostructures of the ketols were identified by X-Ray diffraction. The base-catalysed title reactions gave the cyclic ketols and derived compounds shown below whose structures were identified by X-ray diffraction.
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