Synthesis and structure of Ir4Sn3(CO)6{CH(SiMe3)2}5O3; a heterometallic ‘raft’ with sail hoisted!
Cardin, C. J. Full text not archived in this repository. It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing. To link to this item DOI: 10.1016/0022-328X(93)83389-D Abstract/SummaryHeterometallic raft clusters have been obtained previously for a variety of metals but none for tin and iridium, and more significantly none to date have had metal groups bonded above the raft plane. We report a hexametallic Ir4Sn2 raft to which a third tin group is attached by a single short IrSn bond and three IrOSn bridges.
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