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Synthesis and structure of Ir4Sn3(CO)6{CH(SiMe3)2}5O3; a heterometallic ‘raft’ with sail hoisted!

Cardin, C. J., Power, M. B. and Cardin, D. J. (1993) Synthesis and structure of Ir4Sn3(CO)6{CH(SiMe3)2}5O3; a heterometallic ‘raft’ with sail hoisted! Journal of Organometallic Chemistry, 462 (1-2). pp. 27-28. ISSN 0022-328X

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To link to this article DOI: 10.1016/0022-328X(93)83389-D

Abstract/Summary

Heterometallic raft clusters have been obtained previously for a variety of metals but none for tin and iridium, and more significantly none to date have had metal groups bonded above the raft plane. We report a hexametallic Ir4Sn2 raft to which a third tin group is attached by a single short IrSn bond and three IrOSn bridges.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:23797
Publisher:Elsevier

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