Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromiumTools Cardin, C. J., Cardin, D. J., Kelly, J. M., Norton, R. J., Roy, A., Hathaway, B. J. and King, T. J. (1983) Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromium. Journal of the Chemical Society, Dalton Transactions (4). pp. 671-677. ISSN 1364-5447 Full text not archived in this repository. To link to this article DOI: 10.1039/DT9830000671 Abstract/SummaryReaction of Li(CPhCMe2) with SnCl4 or CrCl3·3thf (thf = tetrahydrofuran) affords the isoleptic compounds Sn(CPhCMe2)4 or [Cr(CPhCMe2)4] respectively. The mode of formation and chemical properties are reported for the chromium species, and the structures of the new compounds, both of which have been determined by single-crystal X-ray analysis, are described.
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