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Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromium

Cardin, C. J., Cardin, D. J., Kelly, J. M., Norton, R. J., Roy, A., Hathaway, B. J. and King, T. J. (1983) Synthesis, properties, and X-ray crystal and molecular structures of homoleptic alkenyls of tin and chromium. Journal of the Chemical Society, Dalton Transactions (4). pp. 671-677. ISSN 1364-5447

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To link to this article DOI: 10.1039/DT9830000671

Abstract/Summary

Reaction of Li(CPhCMe2) with SnCl4 or CrCl3·3thf (thf = tetrahydrofuran) affords the isoleptic compounds Sn(CPhCMe2)4 or [Cr(CPhCMe2)4] respectively. The mode of formation and chemical properties are reported for the chromium species, and the structures of the new compounds, both of which have been determined by single-crystal X-ray analysis, are described.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:23867
Publisher:Royal Society of Chemistry

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