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Homoleptic alkenyls of the early transition metals and related compounds

Cardin, C. J., Cardin, D. J., Kelly, J. M., Norton, R. J. and Roy, A. (1977) Homoleptic alkenyls of the early transition metals and related compounds. Journal of Organometallic Chemistry, 132 (3). pp. 23-25. ISSN 0022-328X

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To link to this article DOI: 10.1016/S0022-328X(00)93731-8

Abstract/Summary

The first stable homoleptic alkenyls of the early transition metals, MRn, (R = C(Ph)=CMe2; M = Ti, Zr, Hf, n = 4; and M = Cr, n = 3) and the related species (C5H5)2MR2 (M = Ti, Zr) and (C5H5)2Zr(Cl)R have been prepared using appropriate organolithium reagents. Cleavage and insertion reactions are reported for the new compounds.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:23888
Publisher:Elsevier

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