Homoleptic alkenyls of the early transition metals and related compoundsTools  Cardin, C. J., Cardin, D. J., Kelly, J. M., Norton, R. J. and Roy, A. (1977) Homoleptic alkenyls of the early transition metals and related compounds. Journal of Organometallic Chemistry, 132 (3). pp. 23-25. ISSN 0022-328X Full text not archived in this repository. To link to this article DOI: 10.1016/S0022-328X(00)93731-8 Abstract/SummaryThe first stable homoleptic alkenyls of the early transition metals, MRn, (R = C(Ph)=CMe2; M = Ti, Zr, Hf, n = 4; and M = Cr, n = 3) and the related species (C5H5)2MR2 (M = Ti, Zr) and (C5H5)2Zr(Cl)R have been prepared using appropriate organolithium reagents. Cleavage and insertion reactions are reported for the new compounds.
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