A closed paramagnetic electron-precise cluster
Bartlett, R. A., Cardin, C. J., Cardin, D. J., Lawless, G. A., Power, J. M. and Power, P. P. (1988) A closed paramagnetic electron-precise cluster. Journal of the Chemical Society, Chemical Communications (4). pp. 312-313. ISSN 0022-4936
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To link to this item DOI: 10.1039/C39880000312
A pentametallic cluster is formed by addition of two [SnR2][R = CH(SiMe3)2] groups to [Os3(CO)8(µ-H)(C6H4PhPCH2PPh2)], in a reaction reversing the ortho-hydrogen abstraction and giving the first closed electron-precise paramagnetic cluster.