Accessibility navigation


Synthesis and crystal structure of a novel octa-aqua bridged star-shaped Ni4K complex

Biswas, R., Drew, M. G. B. and Ghosh, A. (2012) Synthesis and crystal structure of a novel octa-aqua bridged star-shaped Ni4K complex. Inorganic Chemistry Communications, 24. pp. 1-3. ISSN 1387-7003

Full text not archived in this repository.

It is advisable to refer to the publisher's version if you intend to cite from this work. See Guidance on citing.

To link to this item DOI: 10.1016/j.inoche.2012.07.023

Abstract/Summary

A penta-nuclear. star-shaped hetero-metallic compound containing a unique Ni4KO8 core has been synthesized. The X-ray single crystal structure analysis reveals that in the complex, [K(Ni(LH)(2))(4)(OH2)(8)](Br)(ClO4)(8)center dot 11H(2)O (LH=(CH3)(2)HN+(CH2)(3)N=CHC6H4O-) the eight coordinate central K+ ion is encapsulated by four terminal [Ni(LH)(2)](2+) units through the double water bridges between K+ and each Ni(II) ions.

Item Type:Article
Refereed:Yes
Divisions:Faculty of Life Sciences > School of Chemistry, Food and Pharmacy > Department of Chemistry
ID Code:30333
Publisher:Elsevier

University Staff: Request a correction | Centaur Editors: Update this record

Page navigation